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Triply vibrationally yakakwidziridzwa ina-wave mixing spectroscopy inoshandiswa kuona vibrational coherence transfer pakati peasymmetric uye symmetric CO-stretching modes yerhodium(I) dicarbonyl acetylacetonate (RDC).Coherence transfer is an nonradiative transition of a coherent superposition of quantum states kune imwe yakasiyana inopindirana superposition nekuda kwekubatanidza mavibrational modes kuburikidza nekugeza.Zvose zvitatu zvinokurudzira zvinoputika mukuedza zvinopindirana nekubatana kwehuwandu hwehuwandu, asi kufambisa kwekubatana kunoguma mukubatana kutsva nemhando dzakasiyana.Iyo nyowani yekubuda frequency inocherechedzwa ine monochromator inoigadzirisa kubva kune yakasimba peak pane yekutanga excitation frequency.Iyi tekinoroji inogadzirisa nzira dzinosanganisira kufambiswa kwekubatana, kusarura maitiro ekuona anogadzirwa chete neradiative shanduko, uye kugadzirisa kwenguva mamodulation akagadzirwa nekukanganisa pakati penzira dzakasiyana dzekufambisa.Redfield dzidziso inononoka kudzoreredzwa kwechinguva mumiganho yekumanikidza, asi zviri pachena zvakare kuti kufambisa kwekubatana kunotyora fungidziro yenyika inopinzwa mune dzakawanda Redfield dzidziso.Pane kudaro, inoda isiri-Markovian uye yekugezera ndangariro mhedzisiro.RDC inogona kupa muenzaniso wakapfava wekuvandudza dzidziso dzinosanganisira idzi mhedzisiro.