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2,3,4,6-Tetrakis-O-trimethylsilyl-D-gluconolactone, inowanzozivikanwa seTMS-D-glucose, isanganiswa yakasiyana-siyana inowana kushandiswa mune zvakasiyana-siyana zvesayenzi, kusanganisira organic synthesis, carbohydrate chemistry, uye analytical chemistry. TMS-D-glucose inonyanya kukosha mune organic synthesis sezvo inoshanda seboka rekudzivirira kune hydroxyl (OH) inoshanda mapoka mumacarbohydrates.Nekuunza mapoka e-trimethylsilyl (TMS) pamapoka e-hydroxyl eglucose, komisheni inova yakagadzikana uye isingaite, ichibvumira kusarudzwa kwemamwe mapoka e-hydroxyl apo ichisiya vamwe vasina kukanganiswa panguva inotevera yekuchinja kwemakemikari.Iyi nzira yekudzivirira-yekudzivirira inoshandiswa zvakanyanya mumakemikari emakhahydrates kuti uwane inodiwa regioselectivity uye stereochemistry mukubatanidzwa kwemacarbohydrates akaoma, glycoconjugates, uye zvigadzirwa zvechisikigo. yemakhahydrates.Nekushandura makabhohaidhiretsi kuva matrimethylsilyl derivatives, kushanduka kwavo uye kugadzikana kwekupisa kunovandudza, zvichiita kuti zvive zvakakodzera kuongororwa negasi chromatography (GC) uye mass spectrometry (MS).Iyi nzira yekubvisa inosimudzira kunzwisiswa kwekuona, inovandudza kupatsanurwa kwakanaka, uye inogonesa kuzivikanwa kweakasiyana makabhohaidhiretsi mumisanganiswa yakaoma, senge biological samples kana zvigadzirwa zvekudya.TMS-D-glucose inowanawo zvikumbiro mukubatanidzwa kweakakosha reagents uye makemikari probes.Yayo yakasiyana reactivity uye kugadzikana inoita kuti ive yakakosha kutanga zvinhu zvekugadzirira kwemamwe makhahydrates-yakagadzirwa nemakemikari.Vatsvagiri vanogona kushandura iyo trimethylsilyl moiety kana kutsiva iyo glucose moiety kugadzira makomisheni ane chaiwo zvivakwa, senge fluorescent probes, enzyme inhibitors, kana zvinodhaka vanoda zvinodhaka.Izvi zvinobva kune zvakasiyana-siyana zvinogona kushandiswa mune zvakasiyana-siyana zvipenyu uye zvidzidzo zvehupenyu, kusanganisira kufungidzira, kugadzirwa kwezvinodhaka, kana kunzwisisa carbohydrate-protein interactions.Zvisinei, zvakakosha kufunga kuti TMS-D-glucose, seimwe imwe makemikari emakemikari, inoda kubata kwakakodzera uye kuchengeteka. zvekungwaririra.Vatsvaguri vanofanirwa kuve nekupa mhepo yakakwana uye kushandisa midziyo yekudzivirira yakakodzera pavanenge vachishanda nekomboni iyi kudzivirira njodzi dzinogona kuitika pahutano.Uyezve, sezvakaita chero chemakemikari reagent, kuchena, uye kunaka kweTMS-D-glucose zvakakosha kuti uwane migumisiro yakavimbika uye inoberekazve.Muchidimbu, TMS-D-glucose ikemikari yakakosha mukugadzirwa kweorganic, carbohydrate chemistry, uye analytical chemistry.Kugona kwayo kuchengetedza zvakasarudzwa mapoka ehydroxyl mumacarbohydrates, kushanda kwayo mukuongorora makhahydrates, uye kushandiswa kwayo mukubatanidzwa kweakakosha reagents kunoita kuti ive chishandiso chakakosha muzvidzidzo zvakasiyana zvesainzi.Nekushandisa TMS-D-glucose, vaongorori vanogona kufambisira mberi zvidzidzo zvavo mumakemikari ekhabhohaidhiretsi, glycoscience, uye minda ine hukama, zvichibatsira mukugadzirwa kwemakemikari matsva, diagnostics, uye mishonga yekurapa.