Products

Iyo yakaoma [Cp*Ru(MeCN)3]PF6 inoratidzwa kuti inokonzeresa iyo hydrosilylation yeakasiyana maalkynes.Terminal alkynes inokwanisa kuwana alpha-vinylsilane zvigadzirwa zvine yakanaka regioselectivity.Deuterium labeling zvidzidzo zvinoratidza nzira yakachena yekuwedzera yekuwedzera iri kushanda.Iyo yakafanana yakaoma inoshanda mukati mealkyne hydrosilylation, uko kusarudzwa kwakakwana kweiyo trans yekuwedzera nzira inochengetwa.Makirasi akati wandei emukati alkyne substrate makirasi, anosanganisira propargylic doro uye alpha, beta-alkynyl carbonyl makomponi, anobvumira regioselective vinylsilane kuumbwa.Kushivirira kwemhando dzakasiyana-siyana dze silanes kunokosha, kusanganisira alkyl-, aryl-, alkoxy-, uye halosilanes.Izvi zvakanakira zvinoratidzwa mune yakananga synthesis yetriene substrates yesilicon-tethered intramolecular Diels-Alder cycloadditions.